Processes for forming thin, durable coatings of perfluorocarbon ionomers on various substrate materials

ABSTRACT

An improved process for forming a thin, durable coating of a perfluorosulfonated, salt- or acid-form ionomer on a selected substrate, which comprises contacting the substrate with an aqueous, surface active dispersion of the thermoplastic, sulfonyl fluoride precursor of the perfluorosulfonated, salt- or acid-form ionomer, contacting the dispersion-wetted substrate with a salt solution or a strongly ionizing acid solution of a sufficient ionic strength to cause a thin, adherent coating of the precursor particles in said dispersion to be formed on the substrate, then removing excess dispersion and excess salt or acid solution, annealing the coated substrate at an elevated temperature and thereafter converting the precursor to the desired acid or salt form ionomer.

The present invention relates to processes for forming thin coatings ofion-containing polymers on selected substrates, and to the articles madethereby.

BACKGROUND

The known ion-containing polymers include the sulfonated polystyrenes,copolymers of ethylene with alpha-beta unsaturated carboxylic acids suchas acrylic acid or methacrylic acid and the fluorocarbon ionomers. Thesubstantially fluorinated, fluorocarbon ionomers include those havingpendant chains which contain sulfur-based functional groups,phosphorus-based functional groups and carboxylic acid or carboxylatefunctionality. All of these materials, with the exception of thephosphorus-based fluorocarbon ionomers, are presentlycommercially-available.

The substantially fluorinated ionomers which have pendant chainscontaining sulfonic acid functional groups or a salt thereof have beenof particular interest, and commercial examples of such ionomers havebeen produced in the acid form by E. I. DuPont de Nemours & Co., Inc.,under the Nafion™ trademark, where n is 1, 2, 3 etc. and the ratio ofa:b is typically about 7 to 1: ##STR1##

The Dow Chemical Company has produced perfluorinated ionomers having ashorter side-chain (acid-form) structure, wherein n is 0 in thepreceding formula: ##STR2##

The production of these perfluorinated ionomers is described widely inthe literature, for example, in U.S. Pat. No. 3,282,875, 4,329,435,4,330,654, 4,358,545 and 4,940,525, and is well known to those familiarwith the perfluorinated ionomer art. Fundamentally, however, as relatedin U.S. Pat. No. 4,038,213, for example (referencing U.S. Pat. No.3,282,875 and 3,882,093), both types of these perfluorinated ionomerscan be typically prepared by the emulsion copolymerization oftetrafluoroethylene and fluorovinyl ethers that contain sulfonyl groups,and the subsequent transformation of the resulting sulfonyl fluorideprecursor to the acid or salt form ionomer as desired.

As related in commonly-assigned, copending U.S. Ser. No. 08/404,476(currently pending as application Ser. No. 08/625,984) and U.S. Ser. No.08/404,480 (currently pending as application Ser. No. 08/530,645),coatings have been applied from dispersions of these perfluorocarbonionomers by evaporative coating techniques on various substrates, butthe coatings produced by these processes have been less thansatisfactory in one or more respects.

A significant focus of much of the literature to date has been thecoating of polytetrafluoroethylene (PTFE) fibers and/or powders orparticulate materials to make the PTFE fibers and/or particulatematerials water-wettable. In this regard, PTFE possesses a number ofdesirable attributes, including excellent chemical stability. Asignificant barrier has existed however to the use of PTFE in certainapplications, for example in the development of non-asbestos diaphragmsfor chlor-alkali cells, due to the hydrophobic nature of PTFE.

Various efforts have accordingly been made to compensate for or toovercome the hydrophobic character of PTFE in chlor-alkali diaphragmsthrough the incorporation of ion-exchange materials by coating as wellas by other means. An example of these efforts may be found in U.S.Patent No. 4,169,024 to Fang, wherein PTFE (or a similar fluoropolymer)in the form of a powder or fibers, in an unsupported porous or nonporousfilm, in a coating on an inert fabric or in a porous reinforcedstructure (that is, a diaphragm) is chemically modified by reaction witha sulfur- or phosphorus-containing compound.

U.S. Pat. No. 4,720,334 to DuBois et al. is also representative, anddescribes diaphragms containing from 65 to 99 percent by weight of afibrillated fluorocarbon polymer such as PTFE and from 1 to 35 percentof fluorocarbon ionomer (preferably containing carboxylic acid, sulfonicacid, alkali metal carboxylate or alkali metal sulfonate functionality)based on the combined weight of fibrillated fluoropolymer and ionomer,and optionally further containing wettable inorganic particulatematerial. The diaphragm is dried and secured upon an underlying cathodeby being heated to a temperature below the sintering temperature of PTFEfor a time.

The ionomer can be incorporated in the diaphragm of the DuBois patent bycodeposition from a slurry with the ionomer being included as a solid,gel or solution, by being coated on either or both of the fluorocarbonfibrils and inorganic particulate and then deposited from a slurry, orby being extruded in admixture with the fluoropolymer before it isfibrillated. Specific coating processes for coating the PTFE fibrils aredescribed, including mixing PTFE powder with a solution of ionomer in awater-miscible solvent under high shear conditions, then dispersing thecoated fibrils by blending with water and some surfactant.

Thereafter the materials are deposited onto the cathode from theresulting slurry.

Again, however, these efforts have not proven entirely successful. Theaforementioned 08/404,476 and 08/404,480 applications (hereafterreferred to as the '476 and '480 applications) accordingly offeralternative, improved processes for imparting improved wettability toPTFE to be incorporated into a chlor-alkali diaphragm, and especially anon-asbestos chlor-alkali diaphragm, via one or more thin, durablecoatings of the relatively more costly perfluorocarbon ionomer appliedthereto.

In the '476 application, for example, a colloidal, surface activedispersion of a perfluorosulfonate ionomer is used to contact a PTFEsubstrate, after which the coated PTFE substrate, while still wettedwith the dispersion and without an intervening drying step, is exposedto a salt solution or to a solution of a strongly ionizing acid.Annealing of the coated PTFE, as in the bonding at from about 330degrees Celsius to about 355 degrees Celsius of a diaphragmincorporating coated PTFE materials therein, results in a more durable,strongly adhering coating of the ionomer on the PTFE, but can resultalso in a reduced improvement in wettability as compared to an uncoatedPTFE substrate.

The '480 application in turn is particularly directed to a solventless,batch coating process for coating PTFE, for example, with an ionomercoating, whereby the flammability and safety hazards associated with theuse of a lower alcohol in making these sorts of dispersions can beavoided as well as the necessity of a step for evaporating the organicsolvent, and in which PTFE is combined with a colloidal surface activedispersion of a perfluorocarbon ionomer in water and with a salt orstrongly ionizing acid and the mixture is subjected to high shearconditions. Again, annealing conditions associated with the bonding of anon-asbestos diaphragm incorporating the coated PTFE provides improveddurability and adhesion of the coating to the PTFE substrate, withhowever some reduction in wettability being seen generally in comparisonto an unannealed, coated PTFE.

SUMMARY OF THE PRESENT INVENTION

By the present invention, it has been discovered that by

(a) coating a PTFE or other substrate with an aqueous dispersion of thethermoplastic, sulfonyl fluoride precursor of the perfluorosulfonic acidform and perfluorosulfonate salt form ionomers (which corresponds to thelatex produced in the emulsion polymerization of tetrafluoroethylene anda fluorovinyl ether containing sulfonyl groups or which is derivedtherefrom by the addition or removal of water, and/or by the addition ofsurfactant or through the use of a lower alcohol or other added solventfor making aqueous, surface active dispersions of these materials whichwill wet out the substrate to be coated),

(b) contacting the dispersion-wetted substrate with a salt solution or astrongly ionizing acid solution of a sufficient ionic strength to causea thin, adherent coating (which may be continuous but is not necessarilyso) of the precursor particles in the dispersion to be formed on thesubstrate,

(c) removing excess latex and excess salt or acid solution,

(d) annealing the coated substrate at an elevated temperature, and onlythereafter

(e) converting the precursor to the desired acid or salt form ionomer,

the improvement in wettability observed in the '476 and '480applications prior to annealing and more particularly prior to a bondingcycle in a chlor-alkali diaphragm incorporating the same, can besubstantially realized after the bonding, for example, of a non-asbestoschlor-alkali diaphragm including coated poly(tetrafluoroethylene) (PTFE)particulate material or fibers at from about 330 degrees Celsius up toabout 355 degrees Celsius, and the subsequent conversion of theprecursor particles in the bonded diaphragm to the desired,water-wettable ionomer.

A corresponding process is thus provided in a second aspect of thepresent invention, for manufacturing a diaphragm for use in achlor-alkali diaphragm cell. This process comprises

(a) coating a substrate which is to be incorporated into the diaphragmand with respect to which an improvement in hydrophilicity is desired(for example, PTFE fibers or particulate material (which can be inpowdered or granular form), or a fiber composite of the type describedin U.S. Pat. No. 4,853,101 to Hruska et al. which includes PTFE fibersor fibrils) with the thermoplastic, sulfonyl fluoride precursor of theperfluorosulfonic acid form and perfluorosulfonate salt form ionomersvia an aqueous surface active dispersion containing the precursor,

(b) forming an aqueous draw slurry including the coated substrate,

(c) drawing a diaphragm from the draw slurry through vacuum depositionon a diaphragm support,

(d) drying and then bonding the diaphragm under bonding conditions, andthereafter

(e) hydrolyzing the sulfonyl fluoride precursor within the bondeddiaphragm to its perfluorosulfonate, sodium salt form ionomer throughcontact with sodium hydroxide.

One contemplated application of the present invention would, in thecontext of the just-summarized process for manufacturing a diaphragm foruse in a chlor-alkali diaphragm cell, employ the thermoplastic, sulfonylfluoride precursor and/or less expensive and insufficiently chemicallyresistant materials which are coated with the precursor, in directreplacement of some or all of the PTFE or other chemically-resistantfluoropolymer materials conventionally used in non-asbestos diaphragmformulations. The precursor could, for example, be used in replacementof PTFE particulate materials which have been employed as a binder, witha reduction in the bonding temperatures required to bond diaphragms madetherefrom (i.e., from about 330 degrees Celsius or greater for PTFE toin the neighborhood of 300 degrees Celsius or greater for thethermoplastic, sulfonyl fluoride precursor) and a correspondingreduction in the energy requirements to carry out the bonding step.

The desirability of employing the thermoplastic, sulfonyl fluoridepolymer as a binder and bonding at lower temperatures, whether bycausing the coating on PTFE fibers and/or particulate materials in adiaphragm consisting of wettable inorganic particulate materials, PTFEfibers and particulate materials to soften and flow sufficiently to knitthe various constituent materials together into a whole, or by causingthe coating on a less expensive (than PTFE) but insufficientlychemically resistant substrate to soften and flow in a diaphragmcomprised of wettable inorganic particulate materials, the coatedsubstrate and perhaps but not necessarily including PTFE fibers and/orparticulates also, will be dependent on the amount of the sulfonylfluoride precursor which must be employed to effectively bind thematerials of the diaphragm together while still protecting theunderlying substrate from degradation, the comparative cost of thisprecursor and the underlying substrate versus the cost of the PTFE to bereplaced, and any energy savings to be realized by being able to bond ata lower temperature than for the PTFE.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS

The process of the present invention will preferably employ colloidal,surface active aqueous dispersions of the thermoplastic, sulfonylfluoride precursor of an ionomer with an equivalent weight in the rangeof from about 500 to about 1500, and more preferably with an equivalentweight of from about 550 to about 1200. Most preferably, athermoplastic, sulfonyl fluoride precursor will be employed of The DowChemical Company's shorter side chain ionomers having an equivalentweight of from about 550 to about 1000, and especially from about 550 toabout 800.

Dispersions are commercially available or have been made previously ofperfluorosulfonic acid or perfluorosulfonate ionomers of variousequivalent weights in organic solvent-containing systems, for example,in a mixture of water and a lower alcohol such as ethanol or propanol astaught in U.S. Pat. No. 4,433,082 to Grot. These types of dispersionshave been recognized as disadvantageous in the ionomer coating art owingto their flammability and other concerns, and the commonly-assigned '480application referenced above is accordingly particularly directed to asolventless coating process for coating PTFE, for example, wherein thedisadvantages and hazards associated with the use of the prior art'sorganic solvents can be avoided as well as the necessity of a step forevaporating the organic solvent.

The process of the present invention is preferably though notnecessarily also a "solventless" coating process, in employing anaqueous dispersion of the sulfonyl fluoride precursor of thecontemplated ionomers rather than of the ionomers themselves, which mayconsist of the latex resulting from the emulsion polymerization oftetrafluoroethylene and a sulfonyl group-containing fluorovinyl ether toform such precursor or which may be prepared at a variety of weightpercents of the thermoplastic precursor simply by the addition orremoval of water from the latex. The resulting aqueous dispersion may becoated onto a selected substrate in a first embodiment by immersing orotherwise contacting the substrate with the dispersion for an extendedlength of time or with agitation over a lesser period of time.

Most preferably, however, a surfactant will be added to the latex fromthe emulsion polymerization, to increase the speed and ease of wettingout the selected substrate with the dispersion of the thermoplasticsulfonyl fluoride precursor. This surfactant may be the same ordifferent than that which is employed during the initial, emulsionpolymerization giving rise to the precursor, but is most preferably afluorosurfactant containing a sulfonate group (such as a sodiumsulfonate group, as in the exemplified FC-95™ potassium perfluoroalkylsulfonate-based surfactant from Minnesota Mining and Manufacturing Co.,Inc.) which will not be degraded during the bonding cycle of achlor-alkali diaphragm in an especially preferred application for thecoated materials of the present invention.

The dispersion-wetted substrate is then contacted with a salt solutionor a strongly ionizing acid solution of a sufficient ionic strength tocause a thin, adherent coating (which may be continuous but is notnecessarily so) of the thermoplastic sulfonyl fluoride precursorparticles in the dispersion to be formed on the substrate. This mayinvolve stirring the coated substrate into the salt or acid solution(where the coated substrate is a particulate material or fiber) orimmersing the coated substrate in the acid or salt solution (where thesubstrate is a coupon or the like), or will simply and preferablyinvolve adding the salt or acid to the mixture including the substrateand the dispersion. It should be understood that the "salt solution" or"acid solution" specified in the Summary of the Invention above may inthis manner be formed using the water of the dispersion, and that"contacting the dispersion-wetted substrate . . . " accordingly does notnecessarily require that a separate solution be formed of the salt oracid, and indeed a separate acid or salt solution will preferably not beformed.

The acids which can be added to the dispersion/substrate mixture includethose acids which are conventionally known or classified in the art as"strong" acids, for example, nitric acid, hydrochloric acid or sulfuricacid.

Preferably, however, a salt solution will be employed for contacting thedispersion-wetted substrate. Typically in excess of about 1 percent byweight of the salt will be employed in the dispersion/substrate mixture,and preferably the salt will comprise from about 5 percent by weight ofthe mixture to saturation. Salts which have been found generallysuitable for use in the present invention include cations such ashydrogen, alkali metals, alkaline earth metals and transition metals,ammonium and alkylammonium cations in water-soluble combinations withany anion such as sulfate, fluoride, chloride, bromide, iodide,carbonate, phosphate, acetate, hydroxide, nitrate or thiocyanate.

The sodium and magnesium salts have been found especially useful informing essentially continuous coatings on substrates such as PTFE, withsodium chloride, sodium carbonate, sodium acetate and sodium bisulfatebeing still more preferred, and sodium chloride and sodium carbonatebeing especially preferred in the context of forming a draw slurry withPTFE particulates and/or fibers which have been wetted with an aqueousdispersion of thermoplastic sulfonyl fluoride precursor particles.

An evenly thin coating is at this point formed of the sulfonyl fluorideprecursor particles on the substrate, which coating is sufficientlydurable to be rinsed in water without being substantially removed, butwhich can be removed with mechanical abrasion.

The adhesion of the coating is improved, as in the earlier-referencedcommonly-assigned applications, upon removing excess latex and salt oracid solution to recover the coated substrate, and annealing the coatedsubstrate at an elevated temperature below the decomposition temperatureof the ionomer coating. Where the coated substrate is a coupon or someother article, for example, a foraminous support on which has beenformed a diaphragm including coated PTFE fibers and/or particulates, thecoupon or other article may be removed from the mixture with thedispersion or latex and the salt or acid. Where the substrate is inparticulate or fibrous form, the coated substrate can be isolated byfiltration or the like.

Preferably, the annealing will occur near the glass transitiontemperature (T_(g)) of an amorphous polymeric substrate or near thecrystalline melting point of a crystalline polymeric substrate, and thethermoplastic precursor and substrate will be selected such that thethermoplastic precursor will flow freely under the conditions ofannealing, whereby the precursor is able to coat over anomalies andchanges in the surface of the polymeric substrate occasioned by theannealing. It is considered to be largely due to this feature that thesame improvement in wettability seen prior to annealing in thepreviously-referenced, commonly-assigned applications but not maintainedthrough the annealing, for example, of coated PTFE at the sintering orbonding temperatures which are necessary for achieving adequatediaphragm strength and integrity in a chlor-alkali diaphragm includingPTFE in fibrous or particulate form as a binder, is neverthelessrealized after the annealing at such bonding temperatures of PTFE whichhas been coated with particles of the thermoplastic sulfonyl fluorideprecursor of a desired perfluorosulfonate, sodium form ionomer, and thesubsequent conversion of the precursor to the perfluorosulfonate, sodiumform ionomer via a sodium carbonate draw carrier and exposure to sodiumhydroxide.

The substrates which may be coated by the process of the presentinvention are numerous, and may desirably include, for example, fibersand particulates of polymeric substrates such aspolytetrafluoroethylene, polyvinylidene fluoride, fluorinatedethylene-propylene copolymers (FEP), poly(vinyl chloride),polypropylene, chlorotrifluoroethylene or perfluoroalkoxyvinylether-tetrafluoroethylene copolymers (such as are sold under thedesignation Teflon PFA™ by E.I. DuPont de Nemours & Co., Inc.).

A particularly preferred application however is for coatingpolytetrafluoroethylene (PTFE) fibers and/or particulates to make thePTFE fibers and/or particulates water-wettable, particularly when bondedin a chlor-alkali diaphragm and especially a non-asbestos chlor-alkalidiaphragm incorporating significant amounts of PTFE in fibrous orparticulate form or in a fiber composite of the type described in U.S.Pat. No. 4,853,101 to Hruska et al.

A corresponding process is thus provided in a second aspect of thepresent invention, for manufacturing a diaphragm for use in achlor-alkali diaphragm cell. This process in a preferred embodimentcomprises coating PTFE fibers and/or particulates or the just-mentionedfiber composite to be incorporated into the diaphragm and with respectto which an improvement in hydrophilicity is desired with thethermoplastic, sulfonyl fluoride precursor of the perfluorosulfonic acidform and perfluorosulfonate salt form ionomers via an aqueous surfaceactive dispersion containing the precursor, forming an aqueous drawslurry including the coated substrate with sodium carbonate or sodiumchloride, drawing a diaphragm from the draw slurry through vacuumdeposition on a diaphragm support, drying and then bonding the diaphragmunder bonding conditions, and thereafter hydrolyzing the sulfonylfluoride precursor within the bonded diaphragm to itsperfluorosulfonate, sodium salt form ionomer through contact with sodiumhydroxide.

Preferably the draw slurry is formed on a batchwise basis, through theaddition to a draw vat of water, a surfactant, sodium carbonate (morepreferred) or sodium chloride (less preferred), PTFE fibers and/orparticulates and/or a composite fiber as taught in U.S. Pat. No.4,853,101 to Hruska et al., the latex including the thermoplasticsulfonyl fluoride precursor of the desired ionomer, and optionally andpreferably including the addition of various other conventionalhydrophilic diaphragm additives or components, for example, titanates,oxides or silicates, with the order of addition of these draw slurrycomponents not being critical and with some of the components beingoptionally premixed if desired (for example, the water and theprecursor-containing latex). The coating step recited in the precedingparagraph can consequently be accomplished in the process of forming thedraw slurry incorporating the coated substrate resulting from thecoating step, and is in fact preferably accomplished in this manner sothat the recitation of forming the draw slurry including the coatedsubstrate should not in the preceding paragraph be taken as necessarilyrequiring that the substrate be coated in a prior, separate step beforebeing included in the draw slurry.

It is thus contemplated that the present invention will be usefulgenerally with the array of known polymer-modified asbestos diaphragmsand non-asbestos diaphragms, wherein a normally hydrophobic materialsuch as PTFE is incorporated in some form, whether as a fiber, aparticulate material, a combination of fibers and particulates, or in acomposite fiber of the sort described in the Hruska patent, to impartimproved chemical resistance to the diaphragm in question. Aparticularly preferred use will be in making non-asbestos diaphragms inaccordance with the teachings of commonly-assigned U.S. patentapplication Ser. No. 08/525,969, entitled "Novel Non-Asbestos DiaphragmSeparator" and filed concurrently herewith, such application beingincorporated herein by reference.

As more completely described therein, a diaphragm is preferably preparedwhich is comprised of zirconium oxide as a principal, hydrophiliccomponent, PTFE fibers and PTFE particulate material as a bindingmaterial, and which is characterized by a median pore diameter betweenabout 0.1 micrometers and about 0.7 micrometers and a product of theMacmullin number (Nmac) and diaphragm thickness (t, in millimeters)which is between about 5 and about 25 millimeters, where theseparameters are measured as taught in the referenced application. Mostpreferably, the diaphragm will have a median pore diameter between about0.1 and about 0.3 micrometers and an Nmac×t value greater than about 11millimeters.

Preferably the draw slurry employed in constructing these diaphragmswill have a slurry solids concentration between about 190 and about 250grams per liter, and more preferably of about 250 grams per liter toabout 280 grams per liter and higher, with the higher concentrationsgenerally having been found to result in higher caustic currentefficiencies. The slurry will generally contain from about 60 weightpercent to about 81 weight percent of zirconium oxide (typically havinga particle size between about 0.85 microns and about 1.7 microns), fromabout 14 to about 31 percent of a PTFE particulate (for example, Teflon™7C granular PTFE from E. I. DuPont de Nemours & Company, Inc., having anaverage particle size of about 30 microns), and from about 5 to about 9weight percent of PTFE fibers (for example, as shown in the referenced,commonly-assigned application, bleached 0.25 inch long, 3.2 denier PTFEfibers). More preferably and typically, from about 75 to 76 weightpercent will be zirconium oxide, with from 14 to 16 percent of theparticulate PTFE and from 6 to 8 weight percent of PTFE fibers.

Sodium carbonate will preferably be used for the draw carrier, at aconcentration in water which will typically be from about 3 percent byweight to about 20 percent by weight. A suspending agent will preferablybe used, with the suspending agent preferably being aluminum chloride orxanthan gum, most preferably being xanthan gum. The concentration of thesuspending agent will be sufficient to keep the zirconium oxide insuspension, for example, between about 1.0 and about 1.8 grams perliter. An aqueous latex prepared from a thermoplastic, sulfonyl fluorideprecursor (prepared via an emulsion polymerization process) of aperfluorosulfonate ionomer having an equivalent weight of preferablyless than about 800, and preferably of about 650 or less, will be addedwith a sufficient amount of surfactant (typically the same surfactant asused in the emulsion polymerization giving rise to the sulfonyl fluorideprecursor) to wet out the PTFE initially.

The diaphragm is vacuum drawn from the draw slurry on a foraminouscathode which has optionally been stress-relieved beforehand, forexample, by heating a conventional carbon steel cathode to about 500degrees Celsius for an hour. Preferably the drawing is accomplished attemperatures, for example, in the neighborhood of 70 to 100 degreesFahrenheit, and with flow control of residual slurry through the vacuumflow line of the draw vat to prevent pinholing of the diaphragm.

The diaphragm is thereafter dried by continuing application of a vacuumthereon and by oven drying, or simply by oven drying. A slow, uniformdrying is desired in any event to avoid blistering of the diaphragm atthe preferred drying temperatures of from about 40 degrees Celsius toabout 110 degrees Celsius, and where oven drying is employed preferablythe diaphragm is placed in a position in the drying oven wherein the airflow surrounding the diaphragm is relatively free and uniform.

Upon completion of the drying cycle, the diaphragm is bonded in abonding oven at temperatures between about 330 degrees Celsius and about355 degrees Celsius, with preferred temperatures being from 335 degreesCelsius up to about 350 degrees, provided the oven can be controlled atthese temperatures without exceeding 355 degrees Celsius at any area ofthe diaphragm. The sintering of the diaphragm is preferably accomplishedby slowly ramping up to the desired temperature (e.g., at about 2degrees Celsius per minute), maintaining this temperature for a periodof time, for example, about one half hour, and then slowly cooling thediaphragm at a rate for example of about 2 degrees Celsius per minute.

The precursor coated onto the PTFE materials in the diaphragm then inthe presence of sodium hydroxide is converted to the perfluorosulfonate,sodium salt form ionomer, as recited above.

The present invention is more particularly illustrated by the Exampleswhich follow.

ILLUSTRATIVE EXAMPLES Example 1

Tetrafluoroethylene (CF₂ ═CF₂) was copolymerized with CF₂ ═CFOCF₂ SO₂ Fin an emulsion polymerization system, according to the teachings of U.S.Pat Nos. 4,330,654 and 4,358,545, to provide a 640 equivalent weightionomer precursor at 27 percent by weight in water.

A polytetrafluoroethylene (PTFE) coupon was placed directly in the 27weight percent latex from the emulsion polymerization step, and allowedto soak in the latex until wetted with the latex for sixteen hours. Thecoupon was removed from the latex and allowed to air dry at ambienttemperatures, whereupon the dried coupon was heated to 300 degreesCelsius at a rate of 30 degrees per minute and held at 300 degreesCelsius for one hour. The coupon was cooled to ambient temperature andplaced in a 15 weight percent solution of sodium hydroxide in water,which was then heated to 80 degrees Celsius and held there for 1.5hours. The coupon was removed from the NaOH, rinsed with deionizedwater, air dried and the contact angle measured with water.

The method used for making this contact angle measurement, and thosemade in subsequent examples below, involved equilibration of the couponin question in water at ambient temperatures, generally over a period of16 hours or so.

The coupon was thereafter removed from its deionized water soak andpatted dry, then placed on the stage of a Kernco Contact Angle Meter,Model G-1 contact angle measuring device; several measurements (10 to 14measurements) were taken of the contact angle with water of the coatedcoupon on this device. Where the coupon in question would not lie flaton the device, 1/4 inch diameter disks were cut therefrom using a holepunch and the contact angles determined on the sides of the disks whichhad not been exposed to the punch. Two measurements were made using theopposite edges of each disk, and the measurements averaged as with thecoupons.

The average contact angle for this particular coupon was determined tobe 64 degrees, and the coating was not removed with adhesive tape.

Example 2

One gram of Teflon™ 7C granular PTFE was stirred in the same latex asused in Example 1 until wetted with the latex, over about sixteen hours.The coated PTFE was then filtered, and the wet filter cake was heated to300 degrees Celsius at 30 degrees Celsius per minute. After being heldat 300 degrees Celsius for an hour, the material was cooled to ambienttemperature and placed in 15 weight percent sodium hydroxide solutionwith water. The mixture was heated to 80 degrees Celsius and held atsuch temperature for 2 hours, then the solids were isolated byfiltration. The solids were then rinsed with deionized water and placedin a Safranine O™, 3,7-diamino-2,8 dimethyl-5-phenyl-phenaziniumchloride, cationic dye solution (Aldrich Chemical Co., Inc, Milwaukee,Wis.) to check for coating of the PTFE powder. The dyed ionomer coatingwas evident completely surrounding and encapsulating the PTFE particles,and there were no indications of voids, gaps or debonding of the ionomercoating from the PTFE particles.

Example 3

A dispersion was formed in water of 27 percent by weight of the ionomerprecursor, and 2.5 grams of this dispersion were combined with 47.5grams of a 0.2 weight percent solution of FC-95™ surfactant (a potassiumperfluoroalkyl sulfonate-based surfactant, Minnesota Mining andManufacturing Company, Inc.). A PTFE coupon was placed in the resultingdispersion, and 5 grams of NaCl were added. The coupon was removed andallowed to air-dry at ambient temperature, then was heated to 350degrees Celsius and held there for 70 minutes. The coupon was allowed tocool to ambient temperature, then was exposed to a 10 weight percentsolution of NaOH in water at 80 degrees Celsius for one hour. The couponwas rinsed with deionized water and allowed to air-dry. The averagecontact angle of the coated coupon with water over 21 measurements wasfound to be 90 degrees, with a standard deviation of 3.7 degrees. Anuncoated PTFE coupon was for comparison heated to 350 degrees Celsiusfor 70 minutes, then allowed to cool. The average contact angle for theuncoated coupon over 21 measurements was 142.3 degrees, with a standarddeviation of 8.71 degrees.

Example 4

Twenty-five grams of the 27 weight percent ionomer precursor latexformed in Example 1 were mixed with 25 grams of a mixture includingequal parts by volume of ethanol and water. A PTFE coupon was placed inthe mixture, withdrawn and placed in 10 weight percent solution of NaClin water. The coupon was then withdrawn and allowed to air-dry, then washeated to 350 degrees Celsius and held at such temperature for an hour.The bonded coupon was cooled to ambient temperature, and the contactangle found on average to be 69.7 degrees, with a standard deviation of9.1 degrees.

Example 5

Ten grams of the same ionomer precursor dispersion employed in Example 4were mixed with 40 grams of an equal parts by volume mixture of ethanoland water, and a PTFE coupon immersed therein. The coupon was withdrawn,and placed in a 10 weight percent NaCl solution in water. The coupon wasthen withdrawn and allowed to air-dry, whereupon the air-dried couponwas heated to 350 degrees Celsius and maintained at this temperature foran hour. After cooling to ambient temperature, the contact angle onaverage over 10 measurements was determined to be 88.3 degrees Celsius,with a standard deviation of 5.8 degrees.

Example 6

Forty-nine and one half grams (49.5 grams) of the 0.2 weight percentsurfactant solution employed in Example 3 was mixed with 0.5 grams ofthe 27 weight percent ionomer precursor dispersion or latex from Example1, and a PTFE coupon placed in the combination. Five grams of NaCl wereadded to the mixture, the coupon was withdrawn and allowed to air-dry atambient temperature. The dried coupon was then annealed at 350 degreesCelsius for an hour, cooled to room temperature, placed in a 10 weightpercent solution of NaOH in water and hydrolyzed at 80 degrees Celsiusfor an hour. After hydrolysis the coupon was rinsed with deionized waterand allowed to air-dry. The contact angle on averaging 15 measurementswas determined to be 95.5 degrees, with a standard deviation of 8.2degrees.

Example 7

An aqueous latex formed from the emulsion polymerization in Example 1,and containing 27 percent by weight of the 640 EW (equivalent weight)ionomer precursor, was diluted by combining 0.11 grams of the 27 weightpercent latex with 25 grams of deionized water. One gram of PolyramixPMX™ composite fibers from Oxytech Systems Inc. was added and themixture stirred for fifteen minutes, whereupon 2.5 grams of Na₂ CO₃ werestirred into the slurry and stirring continued for thirty minutes.Stirring was stopped, and the solids allowed to settle. Excess liquidwas decanted from the settled fibers, and the coated fibers weredispersed in 20 grams of finely ground sodium chloride and the mixtureheated to 335 degrees Celsius for one hour. The fibers were then cooledto ambient temperature, and placed in 100 grams of a 10 weight percentsolution in water of sodium hydroxide. The sodium hydroxide/fiber slurrymixture was heated to boiling and then allowed to cool to ambienttemperature, and after allowing the fibers to settle excess liquid wasdecanted and the fibers washed with deionized water. The coated annealedfibers were observed to be wettable in water and in the sodium hydroxidesolution.

Example 8

The same materials and procedures were employed for this example as inExample 7, except that the amount initially used of the 27 weightpercent precursor latex was cut in half, from 0.11 grams to 0.055 grams.The coated annealed fibers were again observed to be wettable in waterand in the sodium hydroxide solution.

Comparative Example

For comparison, one gram of the PMX™ composite fibers were stirred indeionized water for 15 minutes, and 2.5 grams of sodium carbonate werethen stirred into the slurry. After thirty minutes of stirring, thefibers were allowed to settle and the excess liquid decanted. Theuncoated fibers were dispersed in 20 grams of finely ground sodiumchloride and the mixture heated to 335 degrees Celsius for an hour. Theheated fibers were cooled to ambient temperature and then were placed in100 grams of 10 percent by weight of sodium hydroxide in water. Thesodium hydroxide/fiber slurry was heated to boiling and then allowed tocool to ambient temperature. The uncoated fibers did not wet out andsettle in either the sodium hydroxide solution or water.

What is claimed is:
 1. A process for manufacturing a diaphragm for usein a chlor-alkali diaphragm cell, comprising:coating atetrafluoroethylene-containing particulate or fibrous substrate which isto be incorporated into the diaphragm and with respect to which animprovement in hydrophilicity is desired with a thermoplastic, sulfonylfluoride precursor of a perfluorosulfonated, salt- or acid-form ionomervia an aqueous, surface active dispersion containing the precursor;forming an aqueous draw slurry including the coated substrate; drawing adiaphragm from the draw slurry through vacuum deposition on a foraminousdiaphragm support; drying and then bonding the diaphragm under bondingconditions; and thereafter hydrolyzing the sulfonyl fluoride precursorwithin the bonded diaphragm to its perfluorosulfonate, sodium salt- oracid-form ionomer.
 2. A process as defined in claim 1, wherein thebonding of the PTFE substrate is conducted at temperatures of about 330degrees Celsius to about 355 degrees Celsius.
 3. A process as defined inclaim 2, wherein the bonding of the PTFE substrate is conducted attemperatures of about 335 degrees Celsius to about 350 degrees Celsius.4. A process as defined in claim 1, wherein the ionomer which is finallycoated onto the substrate is of the following formula when in an acidform: ##STR3##
 5. A process as defined in claim 1, wherein the ionomerwhich is finally coated onto the substrate is of the following formulawhen in an acid form: ##STR4##
 6. A process as defined in claim 4,wherein the ionomer has an equivalent weight in a range of from about500 to about
 1500. 7. A process as defined in claim 6, wherein theionomer has an equivalent weight of from about 550 to about
 1200. 8. Aprocess as defined in claim 5, wherein the ionomer has an equivalentweight in the range of from about 550 to about
 1000. 9. A process asdefined in claim 8, wherein the ionomer has an equivalent weight of fromabout 550 to about
 800. 10. A process as defined in claim 9, wherein theionomer has an equivalent weight from about 550 to about
 650. 11. Aprocess as defined in claim 1, wherein the substrate is a compositefiber comprised of one or more non-organic particulate materials boundto an organic polymer in fiber form.